Pendant Alkenes Promote Cobalt−Cobalt Bond Cleavage in (Alkyne)(binap)tetracarbonyldicobalt(0) Complexes
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Heating (alkyne)(binap)tetracarbonyldicobalt(0) complexes bearing pendant alkenes leads to cleavage of the cobalt−cobalt bond and generation of the mononuclear hydride (binap)(CO)2CoH at 45−55 °C.
创建时间:
2007-03-26



