Oxidative Degradation of Ethers Promoted by Strontium and Barium Tetraphenylimidodiphosphinates
收藏NIAID Data Ecosystem2026-03-06 收录
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The novel M[(OPPh2)2N]2·nTHF (M = Sr (2), Ba (3)) complexes were prepared and characterized. Upon exposure to atmospheric oxygen, 2 and 3 were transformed to the dinuclear species Sr2[(OPPh2)2N]4·2C3H6O3 (4) and Ba2[(OPPh2)2N]4·2C4H8O3 (5), respectively. Compounds 4 and 5 contain coordinated carboxylic acids obtained from the oxidative degradation of DME and THF, respectively, which were used as solvents for crystallization.
创建时间：
2016-05-05
