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Cooperative Bond Scission in a Soft Porous Crystal Enables Discriminatory Gate Opening for Ethylene over Ethane
Here we report a soft porous crystal possessing hemilabile cross-links in its framework that exhibits exclusive gate opening for ethylene, enabling the discriminatory adsorption of ethylene over ethan
NIAID Data Ecosystem70
Solvatomorphism Influence of Porous Organic Cage on C 2 H 2 /CO 2 Separation
Porous organic molecular (POM) materials can exhibit solvatomorphs via altering their crystallographic packing in the solid state, but investigating real gas mixture separation by porous materials wit
NIAID Data Ecosystem30
(Multivariate)-Metal–Organic Framework for Highly Efficient Antibiotic Capture from Aquatic Environmental Matrices
Contamination of aquatic environments by pharmaceuticals used by modern societies has become a serious threat to human beings. Among them, antibiotics are of particular concern due to the risk of crea
NIAID Data Ecosystem10
A Microporous Metal–Organic Framework Constructed from a New Tetracarboxylic Acid for Selective Gas Separation
A new organic ligand of pyrene-containing tetracarboxylic acid and its first metal–organic framework UTSA-72 was designed and synthesized. The MOF has the two-dimensional (4,4) framework topology. The
NIAID Data Ecosystem40
Origins of Acid-Gas Stability Behavior in Zeolitic Imidazolate Frameworks: The Unique High Stability of ZIF-71
Zeolitic imidazolate frameworks (ZIFs) are promising materials for industrial process separations, but recent literature reports have highlighted their vulnerability to acid gases (e.g., SO2, CO2, NO2
NIAID Data Ecosystem20
