The digold(I) diacetylides [4-RC6H9(4-C6H4OCH2C⋮CAu)2], which contain a cyclohexylidene hinge group 4-RC6H9 with R = H or t-Bu, react with diphosphine ligands Ph2PZPPh2 to give the corresponding macro
An oxidant-initiated, substitution process for dihapto-coordinated ligands is described for the {MoTp(NO)(DMAP)} system. Complexes of the form MoTp(NO)(DMAP)(η2-alkene), MoTp(NO)(DMAP)(η2-keto
Photolysis of Cp*Mo(CO)3Me (1; Cp* = η-C5Me5) in the presence of the hydrodisilane HSiMe2SiMeMes2 (Mes = 2,4,6-Me3C6H2) resulted in the formation of the donor-free (silyl)(silylene)molybdenum complex
Reactions of two dinaphthyl phosphines with [Cp*IrCl2]2 have been carried out. In the case of di(α-naphthyl)phenylphosphine (1a), a simple P-coordinated neutral adduct 2a is obtained. However, tert-