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Facile Synthesis of ansa-Zirconocenes Incorporating a Linked Dicarbollyl Ligand via Direct Deboration of Zirconocene Carboranyl Complexes

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Figshare2016-02-23 更新2026-04-29 收录
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ansa-Zirconocene amides incorporating a Me2C-linked cyclopentadienyl–dicarbollyl or indenyl–dicarbollyl ligand were conveniently prepared from direct deboration of the corresponding carboranyl metal complexes using diamines as deboration agents. This represents a new methodology for the preparation of metal dicarbollides.

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2016-02-23
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