Preparation of Bicyclic 1,2,4-Trioxanes from γ,δ-Unsaturated Ketones
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Treatment of γ,δ-unsaturated ketones with hydrogen peroxide and acid provides a rapid entry into the medicinally important 1,2,4-trioxane structure. Alkene substitution that stabilizes carbocationic intermediates proved to be important for the success of this transformation.
创建时间：
2009-02-05
