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Unexpectedly Selective Formation and Reactions of Epoxycyclooctenones under Microwave-Mediated Conditions

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NIAID Data Ecosystem2026-03-06 收录
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Topologically mobile difluorinated cyclooctenones undergo rapid, high-yielding, and completely stereoselective epoxidations with methyl(trifluoromethyl)dioxirane. The epoxides resist conventional hydrolysis but react smoothly in basic media under microwave irradiation to afford unique hemiacetals and hemiaminals in good yield.

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2004-04-15
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