Three new metal–organic frameworks (MOFs) are formed from the reaction of zinc with 5-hydroxyisophthalic acid (H3-5-hip) with a range of additives in dimethylformamide (DMF). The additives include wat
Three zinc(II) phosphonate cluster compounds have been hydrothermally synthesized and structurally characterized. Compound 1 consists of a centered {Zn6(Zn)L6}4− core and two {Zn(Phen)2(H2O)2}2+ count
A bcu topological three-dimensional Mn(II)-organic framework [Mn22(N3)8(L)12(H2O)26·5H2O]∞ (1) (L = 1,2,3-triazole-4,5-dicarboxylate) based on an unprecedented nanoscale cage has been hydrothermally
Metal–organic frameworks demonstrate a wide variety of behavior in their response to pressure, which can be classified in a rather limited list of categories, including anomalous elastic behavior (e.g
