2‑Hydro-2-aminophosphasilene with N–Si–P π Conjugation
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The first 2-aminophosphasilene, [Ar(Me3Si)N]HSiPAr′ (4, Ar = 2,6-iPr2C6H3, Ar′ = 2,6-Mes2C6H3), bearing a hydride ligand on the three-coordinate silicon atom has been synthesized and structurally characterized. Both X-ray data of 4 and DFT calculations on the model compound (H2N)HSiPH (4′) disclosed that the amino group on the silicon atom results in significant N–Si–P π conjugation.
创建时间：
2016-02-20
