High-Temperature Spin Crossover in a Mononuclear Six-Coordinate Cobalt(II) Complex
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The six-coordinate cobalt(II) complex of formula [Co(tppz)2](tcm)2 exhibits a thermally induced spin-crossover behavior from a high spin (S = 3/2) at higher temperatures to a low spin (S = 1/2) at lower temperatures, with the low-spin phase being achieved at T ≤ 200 K.
创建时间：
2016-02-16
